From:Kiskis

Hi! I have a couple of questions about photocards. Which tiers are unobtainable via the beaty shrine? Also is it possible to obtain not discovered cards yet? I notice Secret Jihyo is 006 so there's 004 and 005 to discover

Secret and Celestial are not obtainable by beauty! and yes, you can discover new cards through shrining, it happens all the time :)